Grand marnier
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This is a fairly sweet brandy-based orange liqueur. There are two kinds: the well-regarded red, or Cordon Rouge, and the sweeter and less potent yellow, or Cordon Jaune.
Substitutes
Cointreau (Also an orange flavored liqueur. Not as good for sipping, but works fine for cooking.) OR curaçao (This is also an orange-flavored liqueur, but it's sweeter than Grand Marnier.) OR triple sec (orange-flavored, much sweeter) OR cognac (Not orange flavored, but it's a good substitute for sipping or cooking.) OR Chambord (similar quality, but raspberry-flavored) OR unsweetened orange juice concentrate
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